I've noticed a number of similar questions here on this topic but not quite on the money for the issue I'm seeing. Here's the details:
Windows 2008 DC, 3 Windows 7 Ultimate x64 clients; Profiles share created on the DC (\server\Profiles{user account}) GPO for providing folder redirection on the Documents, Favourites and Desktop folders - Grant Exclusive Rights disabled; redirection for each user account points to \server\Profiles{user account}
Originally, all three workstations were in workgroup mode; I used the 3rd party ProfWiz utility to migrate users A and B to the domain and push their data to the share on the server - worked flawlessly. Both can log-on and see, for example, that their Documents folder is mapped to \server\Profiles{user account} in Windows Explorer.
User C, whole other matter. Things are FUBARed for them. Their profile seems to have become hopelessly tangled and pointing to the wrong place. On log-in they get a basic desktop, not their original one. Their folders appear pointing to the {user account} folder under Profiles and not their {user account}.V2 folder where all their data resides.
When I check their profile on the workstation it shows as Roaming/Roaming. On the DC, their account profile is pointing to \server\Profiles{user account}. Looking at the logs, there isn't anything untoward - just Info messages indicating the operation is correct.
I'm baffled as to why this profile hasn't taken despite having all outward appearances of being correct. Any help gratefully accepted.