Depending on how you setup your Postfix you may be able to use an alias to forward all mail.
edit
Also you can setup a redirect that will do it for you easily.
In /etc/postfix/main.cf add this:
recipient_bcc_maps = pcre:/etc/postfix/forward_bcc.pcre
Then in /etc/postfix/forward_bcc.pcre add this:
/^user@olddomain.com/ user@newdomain.com
This is a bit of a hack but it will work for forwarding specific users from one domain to another.
You also may want to look at this page for how to do some rewriting within Postfix it's self.