I took this from the Netapp best practices guide for aligning partitions on iscsi volumes but it should hold true since your goal is to set the starting sector to the appropriate value. In your case, the 64 can be changed to whatever is applicable per the SQL best practices guide.
Enter expert mode in fdisk and change
the starting LBA of the partition to a
value that is evenly divisible by 8.
In the following example, the default
starting sector is 63 and we will
change it to 64 because 64 is evenly
divisible by 8. The default starting
sector chosen by fdisk is based on the
size of the LUN. fdisk uses the LUN
size to calculate a pseudo geometry
which can vary between different
versions of fdisk.
Command (m for help): x
Expert command (m for help): b
Partition number (1-4): 1
New beginning of data (63-62926604, default 63): 64