The team I'm on recently switched to .Net, so I'm learning C# and am becoming the team WCF guru.
At home, I'm still doing some PHP work. I've also started picking up Python for some desktop work.
I also have a smattering of design experience, having done most of the design work for several of our web apps. Our graphic artists make it pretty with graphics, but I do the design.
Finally, I love raytracing with POV-Ray, which you can see at my deviantArt account, listed as my website.