I eventually managed to find what I was looking for with a Google search:
http://community.spiceworks.com/topic/128389-is-it-possible-to-delete-all-offline-network-printers-with-vbscript-on-logon
The VB script I needed was this:
strComputer = "."
Set objWMIService = GetObject("winmgmts:\\" & strComputer & "\root\cimv2")
Set colInstalledPrinters = objWMIService.ExecQuery _
("Select * From Win32_Printer Where Network = True")
For Each objPrinter in colInstalledPrinters
objPrinter.Delete_
Next
I have tested it thoroughly and it leaves all PDF printers and locally-installed printers unchanged- just targeting network printers as I wanted.
Hopefully this helps other people who are trying to achieve a really slick, Group Policy-deployed printer setup with no Command Prompt windows flashing on the screen at logon.
Note: due to the mixed nature of our environment (XP, Win7 x86 and Win7 x64) I logged on as admin myself on each PC once to make sure the appropriate drivers for all 3 printers were installed successfully. So I am not relying on this script to install the drivers (although it can easily be tailored to do that). Our 2 Win7 x64 machines could not pull the right drivers from the network for some reason (perhaps because printers shared on an XP x86 machine?) By logging in as admin (and manually pointing to the correct .ini file where needed) I was able to ensure users had no unexpected driver issues. The script just ensures the correct print queues are shown for each user on each PC. I was not sure how to tailor the script to pick the right driver version for multiple OS types, and did not want to leave anything to chance.
Anyway, all combined, the entire VB script does the following 3 things at logon:
1) Deletes all existing print queues in that user profile:
strComputer = "."
Set objWMIService = GetObject("winmgmts:\\" & strComputer & "\root\cimv2")
Set colInstalledPrinters = objWMIService.ExecQuery _
("Select * From Win32_Printer Where Network = True")
For Each objPrinter in colInstalledPrinters
objPrinter.Delete_
Next
2) Adds multiple print queues as required:
Dim multiPrinter, UNCpath1, UNCpath2, UNCpath3
UNCpath1 = "\\server\printer1"
UNCpath2 = "\\server\printer2"
UNCpath3 = "\\server\printer3"
Set multiPrinter = CreateObject("WScript.Network")
multiPrinter.AddWindowsPrinterConnection UNCpath1
multiPrinter.AddWindowsPrinterConnection UNCpath2
multiPrinter.AddWindowsPrinterConnection UNCpath3
3) Sets the correct default printer:
Set WshNetwork = CreateObject("WScript.Network")
PrinterPath = "\\server\printer1"
PrinterDriver = "PrinterDriver"
WshNetwork.AddWindowsPrinterConnection PrinterPath, PrinterDriver
WshNetwork.SetDefaultPrinter "\\server\printer1"
WScript.Quit
Enjoy!