I'm a little confused as to how to access the VPN network I've just connected to on a mac.
I've successfully connected, but don't know what to do now.
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Depends upon what you are trying to do.
If you want to connect to a network share you can use the connect to server option from the finder. You can enter smb://servername and you will be presented with a list of available resources on the server.
If you want to control another computer you can use the MS RDP client for the Mac.