AD uses both Kerberos and LDAP.
https://technet.microsoft.com/en-us/library/2005.01.activedirectory.aspx
I am going to boil this down simplistically, since it
seems you need to start from the very beginning. Kerberos is the
default authentication (and authorization) protocol used by Active
Directory, though it is classically thought of as an authentication
protocol only. Kerberos is platform-independent and was invented at
MIT, and Microsoft later adopted it beginning Windows 2000 Active
Directory to provide you single sign-on access (which means you only
enter your password one time when you first logon) to subsequent
network resources on your network and not challenge you again for a
username and password. Kerberos is involved in nearly everything,
from the moment you first logon to access your computer, to accessing
the SYSVOL share on Domain Controllers, by handing out what are known
as tickets, which are encrypted. Kerberos largely replaced NTLM, an
older and Microsoft’s original (with Windows NT) authentication
protocol. LDAP is also an authentication and authorization protocol,
and also methodology of organizing objects such as users, computers,
and organizational units within a directory, such as Active Directory.
It is basically the list view of what you see when you open up the
Active Directory Users and Computers console. Kerberos is more secure
than LDAP, and they are often used together. For example, when you
open up the Active Directory Users and Computers console, your
computer first obtains a ticket to access your Domain Controller and
then uses LDAP to actually use the console itself when working with
objects such as users or OUs. Kerberos and LDAP allow you to run a
heterogeneous network of Windows, Linux, UNIX and even Apple Mac
clients on a Microsoft Active Directory network.
https://social.technet.microsoft.com/Forums/en-US/cb6b05cc-3162-456d-a987-d113821fbdd6/difference-between-kerberos-and-ldap-in-active-directory?forum=winserverDS
And yes, it is encrypted OOB.